
Biomimetics of the [FeFe]-hydrogenase enzyme: Identification of kinetically favoured apical-basal [Fe2(CO)4(μ-H){κ2-Ph2PC(Me2)PPh2}(μ-pdt)]+ as a proton-reduction catalyst
Keywords: [FeFe]-hydrogenase; Diphosphine; Dithiolate; Diiron; Chelating; Biomimetic; DFT;