Kinetics and mechanism of cyclohexane oxidation on MnAPO-5 catalysts
Keywords: اثرات ایزوتوپ; Cyclohexane oxidation; MnAPO-5; Kinetics; Isotope effects
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Anharmonic dynamics: melting and mass transfer in liquid
Keywords: اثرات ایزوتوپ; 64.70.Dv; 61.20.--p; 05.45.--aMelting; Water; Self-diffusion; Viscosity; Isotope effects
Stereochemistry and deuterium isotope effects associated with the cyclization-rearrangements catalyzed by tobacco epiaristolochene and hyoscyamus premnaspirodiene synthases, and the chimeric CH4 hybrid cyclase
Keywords: اثرات ایزوتوپ; Sesquiterpenes; Eremophilanes; Spirovetivane; Germacrane; Enzyme mechanisms; Stereochemistry; Deuterium labeling; Isotope effects; Rearrangements; Cyclizations; Carbocations
Isotope effects and the mechanism of deoxygenation of epoxides with dichlorocarbene
Keywords: اثرات ایزوتوپ; Isotope effects; Mechanism; Deoxygenation; Epoxide; Coarctate;
Isotope effects and the mechanism of fragmentation of epoxy imino-1,3,4-oxadiazolines
Keywords: اثرات ایزوتوپ; Isotope effects; Mechanism; Fragmentation; Coarctate;
Isotope effects and the mechanism of palladium-catalyzed allylic alkylation
Keywords: اثرات ایزوتوپ; Isotope effects; Mechanism; Allylic alkylation; Allylation; Palladium;
Geometry of the CaOCH3 radical from isotope effects in the AË2E-XË2A1 transition
Keywords: اثرات ایزوتوپ; Laser excitation spectroscopy; Isotope effects; Isotopic substitution; Symmetric top; Laser ablation; CaOCH3; Alkaline-earth compounds;
Synthetic and mechanistic studies on ruthenium dicarbonyl complexes containing PhP(CH2CH2CH2PCy2)2 (Cyttp) ligand
Keywords: اثرات ایزوتوپ; Ruthenium complexes; Carbonyl complexes; Triphosphine complexes; syn–anti Isomerism; Ligand substitution; Isotope effects; Mechanism
Multinuclear magnetic resonance studies of gaseous and liquid dimethyl ethers
Keywords: اثرات ایزوتوپ; NMR spectra; Nuclear magnetic shieldings; Gas phase; Isotope effects; Intermolecular effects;
The serine acetyltransferase reaction: acetyl transfer from an acylpantothenyl donor to an alcohol
Keywords: اثرات ایزوتوپ; Serine acetyltransferase; Left-handed parallel β-helix; Cysteine synthesis; Acid-base mechanism; Isotope effects; Kinetic mechanism;
19F and 13C spectra of fluorinated and partially fluorinated vinyl alkyl ethers
Keywords: اثرات ایزوتوپ; 13C; Fluorine; NMR spectra; Spin-spin coupling; Ethers; Vinyl compounds; Molecular geometry; Isotope effects; Monomers;
Mechanistic studies on reaction of [ReH4(η2-H2)(Cyttp)]+ with ketones to give the hydrido-oxo complex [ReH2(O)(Cyttp)]+ (Cyttp = PhP(CH2CH2CH2PCy2)2)
Keywords: اثرات ایزوتوپ; Mechanism; Rhenium complexes; Hydrido-oxo complexes; Ketone complexes; Oxygen transfer; Isotope effects;
Deuterium isotope differences in 2-propanone, (CH3)2CO/(CD3)2CO: a high-pressure sound-speed, density, and heat capacities study
Keywords: اثرات ایزوتوپ; Speed of sound; Density; Heat capacities; Pressure; Isotope effects; Acetone;
Steric compression and twist in o-hydroxy acyl aromatics with intramolecular hydrogen bonding
Keywords: اثرات ایزوتوپ; Isotope effects; Hydrogen bonding; NMR; X-ray diffraction; Structure calculations; Aim analysis;
Competitive reactions and diastereoselective CH bond activation in the McLafferty rearrangement of photoionized 3-methyl valeramide
Keywords: اثرات ایزوتوپ; CH activation; Distonic ions; Ion-neutral complexes; Isotope effects; Mass spectrometry; Steric effects;