
Non-chemical proton-dependent steps prior to O2-activation limit Azotobacter vinelandii 3-mercaptopropionic acid dioxygenase (MDO) catalysis
Keywords: Non-heme mononuclear iron; Thiol dioxygenase; Solvent isotope effects; Proton inventory; Viscosity effects; CDO; cysteine dioxygenase; MDO; 3-mercaptopropionic acid dioxygenase; 3mpa; 3-mercaptopropionic acid; cys; l-cysteine; ca; cysteamine (2-aminoethan