Keywords: تعداد گردش; bpy; 2,2â²-bipyridine; Im; imidazole; MLCT; metal-to-ligand charge transfer; NAD; nicotinamide adenine dinucleotide; NAP; naphthyridine; NHC; N-heterocyclic carbene; phen; 1,10-phenanthroline; pic; 4-picoline; PPh3; triphenylphosphine; py; pyridine; TN;
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Keywords: تعداد گردش; 4DHBP; 4,4â²-dihydroxy-2,2â²-bipyridine; 6DHBP; 6,6â²-dihydroxy-2,2â²-bipyridine; Acac; acetylacetonate; Acriphos; 4,5-bis(diphenylphosphino)acridine; Bpy; 2,2â²-bipyridine; Cp; cyclopentadienyl; Cp*; pentamethyl cyclopentadienyl; DMOA; N,N-dimethylo
Keywords: تعداد گردش; CuAAC; Copper-Catalyzed Azide-Alkyne Cycloadditions; PhSH; thiophenol; alloc; allylcarbamate group; DAPI; 4â²,6-diamidine-2â²-phenylindole; EtBr; ethidium bromide; TON; turnover number; GSH; glutathione; PBS; phosphate buffered saline; TPP; triphenylp
Keywords: تعداد گردش; 1,4-biyb; 1,4-bis(imidazol-1-ylmethyl)benzene; 2,6-ndc; 2,6-naphthalenedicarboxylate; 2-cmsnH2; 2-carboxymethylsulfanyl nicotinic acid; 3-dpye; N,Nâ²-bis(3-pyridinecarboxamide)-1,2-ethane; 4,4â²-bpy; 4,4â²-bipyridine; 4,4â²-obb; 4,4â²-oxybis(benzoate
Small-molecule models of tyrosinase: From ligand hydroxylation to catalytic monooxygenation of external substrates
Keywords: تعداد گردش; BIMZ; bis(1-methylimidazol-2-yl)methane; BPM; 1,1â²-methylenebis-1H-pyrazole; CO; catechol oxidase; CT; charge transfer; dmBPM; 1,1â²-methylenebis(3,5-di-methyl-1H-pyrazole; DFT; density functional theory; l-DOPA; 3,4-dihydroxy-l-phenylalanine; 2,4-DTBP
Catalyst recycling-A survey of recent progress and current status
Keywords: تعداد گردش; AAS; atomic absorption spectroscopy; AB; ammonia-borane (H3N:BH3); acac; acetylacetonate; BAIB; [bis(acetoxy)iodo]benzene; bdmi; 1-butyl-2,3-dimethylimidazolium; BARF; tetrakis-[3,5-bis(trifluoromethyl)phenyl]borate; BINAM; 1,1â²-binaphthyl-2,2â²-diam
Rational design of metalloenzymes: From single to multiple active sites
Keywords: تعداد گردش; UAAs; unnatural amino acids; Rd; rubredoxin; EPR; electron paramagnetic resonance; Az; azurin; SOR; superoxide reductase; PDB; protein data bank; 6-PGLac; 6-phosphogluconolactonase; H-bond; hydrogen-bond; NIR; nitrite reductase; ET; electron transfer; 3SC
Keywords: تعداد گردش; acac; acetylacetonate; All; allyl; An; methoxyphenyl; BARF; tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; Bn; benzyl; Bu; n-butyl; Cp; η5-cyclopentadienyl; Cpâ²; η5-methylcyclopentadienyl; CPE; controlled potential electrolysis; CV; cyclic voltammetr
Keywords: تعداد گردش; O2â¢â¾; superoxide; ONOO-; peroxynitrite; ClO-; hypochlorite; MnTE-2-PyP5+; Mn(III) meso-tetrakis(N-ethylpyridinium-2-yl)porphyrin (also known as AEOL10113, BMX-010); MnTE-3(or 4)-PyP5+; Mn(III) meso-tetrakis(N-ethylpyridinium-3(or 4)-yl)porphyrin;
Keywords: تعداد گردش; High throughput biochemical characterization of terpene synthasesSteady-state kinetics; Catalytic efficiency; Turnover number; Terpene synthases; Colorimetric assay; High-throughput; Screening; Malachite greenTPS, terpene synthase; MG, malachite green; FP
Kinetic analysis of cellulose synthase of Gluconacetobacter hansenii in whole cells and in purified form
Keywords: تعداد گردش; AcsA-AcsB; AcsC; AcsD; Acetobacter; Turnover number;
Effects of mutations of non-catalytic aromatic residues on substrate specificity of Bacillus licheniformis endocellulase cel12A
Keywords: تعداد گردش; rBLCel; wild-type recombinant cellulase enzyme; MTCC; Microbial Type Culture Collection; LB; Luria-Bertani; kcat; turnover number; Km; Michaelis constant; PDB; Protein Data Bank; Vmax; maximum velocity; cel12A; endocellulase gene; CMC; Carboxymethylcellul
Synthesis of MOFs for heterogeneous catalysis via linker design
Keywords: تعداد گردش; MOFs; metal-organic frameworks; PCNs; porous coordination networks; PCPs; porous coordination polymers; PSM; post-synthetic modifications; SBUs; secondary building units; TCPP; tetrakis(4-carboxyphenyl)porphyrin); MMPF; metal-metalloporphyrin framework;
Generating and optimizing the catalytic activity in UiO-66 for aerobic oxidation of alkenes by post-synthetic exchange Ti atoms combined with ligand substitution
Keywords: تعداد گردش; Heterogeneous catalysis; Aerobic oxidation of alkenes; Metal-organic frameworks; UiO-66; MOF; metal-organic framework; TON; turnover number;
Heteroleptic diimine-diphosphine Cu(I) complexes as an alternative towards noble-metal based photosensitizers: Design strategies, photophysical properties and perspective applications
Keywords: تعداد گردش; ACN; acetonitrile; ATRA; atom transfer radical addition; bpy; 2,2â²-bipyridine; CDC; cross-dehydrogenative coupling; DCM; dichloromethane; DFT; density functional theory; DHA; dihedral angle; DMF; dimethylformamide; DSSC; dye sensitized solar cell; FC; F
Reaction mechanisms of catalytic photochemical CO2 reduction using Re(I) and Ru(II) complexes
Keywords: تعداد گردش; 6Mesbpy; 6,6â²-mesityl-2,2â²-bipyridine; BIH; 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole; BNAH; 1-benzyl-1,4-dihydronicotinamide; bpy; 2,2-bipyridine; CV; cyclic voltammetry; dmb; 4,4â²-dimethyl-2,2â²-bipyridine; D; electron donor; DMA; N,
Beyond pristine metal-organic frameworks: Preparation and application of nanostructured, nanosized, and analogous MOFs
Keywords: تعداد گردش; Composite; Defects; Hierarchical/hollow structure; Metal-organic-framework; Nanoparticle; Nanostructure; BAS; bottle around ship; BDC; 1,4-benzenedicarboxylate; BTC; 1,3,5-benzenetricarboxylate; CD; cyclodextrin; CNT; carbon nanotubes; CTAB; cetyltrimet
Coordination chemistry of 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. Part III. Variations on a theme: Novel architectures, materials and applications
Keywords: تعداد گردش; PTA; 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane; HPTA; 1-H-1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane; mPTA; 1-methyl-1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane; PTABn; 1-benzyl-1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane; PTAS; 1,3,5-triaza-7-
Promoted electrocatalytic ability of the Pd on doped Pt in NiO-MgO solid solution toward methanol and ethanol oxidation
Keywords: تعداد گردش; Turnover number; Fuel cell; Temkin isotherm; Electrooxidation; Palladium; Nanocatalyst;
Improving β-glucosidase biocatalysis with deep eutectic solvents based on choline chloride
Keywords: تعداد گردش; DESs; deep eutectic solvents; pNPG; p-nitrophenyl-β-glucopyranoside; pNP; p-nitrophenol; [EMIM][BF4]; 1-ethyl-3-methylimidazolium tetrafluoroborate; ILs; ionic liquids; HBD; hydrogen bond donor; HBA; hydrogen bond acceptor; dimethyl sulfoxide; DMSO; ChCl
Cytochrome P450 4A11 inhibition assays based on characterization of lauric acid metabolites
Keywords: تعداد گردش; CYP4A11; Reaction phenotyping; HET0016; Plumbagin; Lauric acid metabolism; HLM; human liver microsomes; CYP; cytochrome P450; 20-HETE; 20-hydroxyeicosatetraenoic acids; LC-MS/MS; liquid chromatography-tandem mass spectrometry; IC50; the half maximal inh
Molecular catalysis of the electrochemical and photochemical reduction of CO2 with Fe and Co metal based complexes. Recent advances
Keywords: تعداد گردش; TON; turnover number; TOF; turnover frequency; CS; catalytic selectivity; CV; cyclic voltammetry; SHE; standard hydrogen electrode; FE; faradaic efficiency; PS; photosensitizer; SD; sacrificial electron donor; âPS; photosensitizer excited state; PSâ;
Nitroxides protect horseradish peroxidase from H2O2-induced inactivation and modulate its catalase-like activity
Keywords: تعداد گردش; ABTS2-; 2,2â²-Azino-bis(3-ethylbenzthiazoline-6-sulfonic acid; R-+â¢PorFeIV=O; compound I; R-PorFeIV=O; compound II; R-PorFeIIIO2â¢- â R-PorFeIIO2; compound III; 3-CP; 3-carbamoyl proxyl; EPR; electron paramagnetic resonance; R-PorFeIII; heme pro
Rearranging from 6- to 7-coordination initiates the catalytic activity: An EPR study on a Ru-bda water oxidation catalyst
Keywords: تعداد گردش; EPR; electron paramagnetic resonance; H2bda, 2; 2â²-bipyridine-6,6â²-dicarboxylic acid; PSII; Photosystem II; WOCs; water oxidation catalysts; bpy; 2,2â²-bipyridine; bda2â, 2; 2â²-bipyridine-6,6â²-dicarboxylate; TOF; turnover frequency; TON; turnov
Carbon dioxide reduction with homogenous early transition metal complexes: Opportunities and challenges for developing CO2 catalysis
Keywords: تعداد گردش; 18-crown-6; 1,4,7,10,13,16-hexaoxacyclooctadecane; Ac; acetyl group; bpy; 2,2â²-bipyridine; bpy-R; substituted 2,2â²-bipyridine ligand; Cp; cyclopentadienyl anion; Cpâ²; methylcyclopentadienyl anion; Cp*; pentamethylcyclopentadienyl anion; DFT; Density
Multidentate N-heterocyclic carbene complexes of the 3d metals: Synthesis, structure, reactivity and catalysis
Keywords: تعداد گردش; δ; Chemical shift; 1D; One dimension; 2D; Two dimensions; Ac; Acetate; Acac; Acetylacetonate; Ad; Adamantyl; Ar; Aryl; BARF; Tetrakis(3,5-di-trifluoromethylphenyl)borate); Bipy; 2,2â²-bipyridine; Bu; Butyl; Bn; Benzyl; COD; Cyclooctadiene; COE; Cyclooct
Room temperature selective reduction of nitrobenzene to azoxybenzene over magnetically separable urchin-like Ni/Graphene nanocomposites
Keywords: تعداد گردش; Nanocomposite; Azoxybenzene; Selective reduction; Magnetically recyclable; Turnover number
Near real-time determination of metabolic parameters for unquenched 6-mercaptopurine and xanthine oxidase samples using capillary electrophoresis
Keywords: تعداد گردش; 6-Mercaptopurine; Xanthine oxidase; Capillary electrophoresis; Michaelis constant; Turnover number
Rapid synthesis of novel flowerlike K0.46Mn2O4(H2O)1.4 hierarchical architectures and their catalytic degradation of formaldehyde in aqueous solution
Keywords: تعداد گردش; Birnessite; Nanoflowers; Formaldehyde; Acetylacetone; Turnover number
Comparison of dynamics of wildtype and V94M human UDP-galactose 4-epimerase-A computational perspective on severe epimerase-deficiency galactosemia
Keywords: تعداد گردش; GALE; UDP-galactose 4â²-epimerase; HsGALE; human UDP-galactose 4â²-epimerase; kcat; turnover number; OMIM #230400; type I galactosemia, galactose 1-phosphate uridylyltransferase deficiency; OMIM #230200; type II galactosemia; OMIM #230350; type III gala
Photocatalytic reduction of CO2 under supercritical CO2 conditions: Effect of pressure, temperature, and solvent on catalytic efficiency
Keywords: تعداد گردش; Photocatalytic CO2 reduction; Rhenium catalyst; Supercritical CO2; Turnover number; Turnover frequency
Performance of a biomimetic oxidation catalyst immobilized on silica particles
Keywords: تعداد گردش; Biomimetic; Catalysis; Cobalt porphyrin; Immobilization; Silica particles; X-ray Photoelectron Spectroscopy; Magnetic particles; Turnover number; Turnover frequency
A [2 × 2] Cu4 molecular grid and a Mn5 cluster derived from a 1-(2-pyridyl)pyrazole based polytopic ligand – Synthesis, structure, magnetic properties and catalytic activity in the allylic oxidation of cyclohexene
Keywords: تعداد گردش; Tetranuclear Cu(II); Pentanuclear Mn(II); Ferromagnetic; Antiferromagnetic; Turnover number
Transition metal free transfer hydrogenation of ketones promoted by 1,3-diarylimidazolium salts and KOH
Keywords: تعداد گردش; Imidazolium salt; Transfer hydrogenation; Metal-free catalyst; Turnover number;
Single site anchored novel Cu(II) catalysts for selective liquid–gas phase O2 oxidation of n-alkanes
Keywords: تعداد گردش; Cu catalyst; Oxidation; n-alkanes; Batch reactor; Turnover number
Boophilus microplus cathepsin L-like (BmCL1) cysteine protease: Specificity study using a peptide phage display library
Keywords: تعداد گردش; rBmCL1; recombinant Boophilus microplus cathepsin L-Like; Kcat; turnover number; Ki; inhibition constant; Km; Michaelis-Menten constant; Vmax; maximum velocity; Cysteine proteases; Rhipicephalus (Boophilus) microplus; Protein expression; Enzyme kinetic;
First in-gel detection and purification of human xylosyltransferase II
Keywords: تعداد گردش; Xylosyltransferase; Proteoglycan; Glycosaminoglycan; Turnover number; Catalytic efficiency; Pichia pastoris; Heparin;
Environmentally friendly synthesis of biaryls: Suzuki reaction of aryl bromides in water at low catalyst loadings
Keywords: تعداد گردش; Suzuki reaction; Biaryls; Turnover number; Green chemistry;
The oxygenation of cyclohexane under GifIV conditions – The catalytic behaviour of iron complexes
Keywords: تعداد گردش; Gif catalysis; Iron; Picolinic acid; Cyclohexane; Turnover number; Oxygenation
Catalytic oxidation performance of the α-Keggin-type vanadium-substituted heteropolymolybdates: A density functional theory study on [PVnMo12−nO40](3+n)− (n=0–3n=0–3)
Keywords: تعداد گردش; Vanadium(V)-substituted heteropolymolybdates; Oxidation catalyst; Redox properties; Benzene hydroxylation; Turnover number; O3LYP
An efficient Stille cross-coupling reaction catalyzed by Pd(OAc)2/DAB-Cy catalytic system
Keywords: تعداد گردش; Pd(dba)2/DAB-Cy; Stille cross-coupling reaction; Aryl halide; Organotin compound; Turnover number;
Some general principles for designing electrocatalysts with hydrogenase activity
Keywords: تعداد گردش; app.; apparent; bipy; bipyridine; buS42â; 1,2-bis(2-mercapto-3,5-di-t-butylphenylthio)ethane dianion; CB; conduction band; Cpâ; cyclopentadienyl anion; Cp*â; pentamethylcyclopentadienyl anion; Cy; cyclohexyl; cyclam; 1,4,8,11-tetraazacyclotetradecan
Palladium-catalysed reactions of alcohols. Part B: Formation of C-C and C-N bonds from unsaturated alcohols
Keywords: تعداد گردش; Palladium; Alcohols; Arylation; Vinylation; Amination; η3-Allylpalladium; Umpolung; BINAP; 2,2â²-bis(diphenylphosphino)-1,1â²-binaphthyl; bmim; 1-n-butyl-3-methylimidazolium; Cy; cyclohexyl; cat.; catalytic; conv.; conversion; dba; dibenzylidene aceton
Palladium-catalysed reactions of alcohols. Part D: Rearrangements, carbonylations, carboxylations and miscellaneous reactions
Keywords: تعداد گردش; Palladium; Catalysis; Alcohols; Rearrangement; Cleavages; Carbonylations; Carboxylations; BINAP; 2,2â²-bis(diphenylphosphino)-1,1â²-binaphthyl; cat.; catalytic; conv.; conversion; dba; dibenzylidene acetone; de; diastereoisomeric excess; ee; enantiomeri
Chemical and biochemical transformations in ionic liquids
Keywords: تعداد گردش; Hacac; Acetylacetone; [R(Rf)taz][Y]; 1,4-Alkyl(polyfluoroalkyl)-1,2,4-triazolium ionic liquids; [taz][X]; 1-Alkyl-4-polyfluoroalkyl-1,2,4-triazolium halides; (DHQ)2PHAL; 1,4-Bis(9-O-dihydroquininyl)phthalazine; (DHQD)2PHAL; 1,4-Bis(9-O-dihydroquinidinyl)p
Palladium-catalysed reactions of alcohols. Part C: Formation of ether linkages
Keywords: تعداد گردش; Palladium; Alcohols; Etherification; Heterocyclisation; Oxypalladation; η3-Allylpalladium; atm; atmosphere; BINAP; 2,2â²-bis(diphenylphosphino)-1,1â²-binaphthyl; cat.; catalytic; COD; 1,5-cyclooctadiene; conv; conversion; Cy; cyclohexyl; dba; dibenzyli