کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10128959 | 1645163 | 2019 | 32 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Local structure and magnetic properties of Mn3+-O-Fe3+ superexchange interaction in an oxygen-vacant perovskite: Experimental and theoretical study
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موضوعات مرتبط
مهندسی و علوم پایه
فیزیک و نجوم
فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this work we report an experimental and theoretical study on the local structure and magnetic properties of Mn3+-O-Fe3+ superexchange interaction for an oxygen-vacant perovskite PrBaMnFeO5+δ with δâ¯â¼â¯0.5. Structural studies were performed by high resolution X-Ray diffraction technique in normal and anomalous scattering, modeled using an orthorhombic biphasic system corresponding to an oxygen-rich and oxygen-poor stoichiometries. Mössbauer spectroscopy showed the presence of two orthorhombic iron sites, one ascribed to a fully octahedral coordination and another, highly distorted, ascribed to a pyramidal coordination, in full agreement with theoretical DFTâ¯+â¯Uâ¯+â¯SO calculations. The samples showed a spin-glass transition at â¼20â¯K and mainly the presence of Mn3+-O-Fe3+ type-G antiferromagnetic superexchange interactions. However, our theoretical calculations using first principles also suggested that the presence of oxygen vacancies in certain conditions could be possibly promoting local ferromagnetic interactions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetism and Magnetic Materials - Volume 469, 1 January 2019, Pages 224-230
Journal: Journal of Magnetism and Magnetic Materials - Volume 469, 1 January 2019, Pages 224-230
نویسندگان
Mariano Romero, Ricardo Faccio, Helena Pardo, BenjamÃn Montenegro, Diego Richard, Javier MartÃnez, Azucena Marisol Mudarra Navarro, Alvaro W. Mombrú,