کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10155603 | 1666356 | 2019 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Facile synthesis of hierarchically γ-Al2O3@C yolk-shell microspheres for lithium-sulfur batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The practical application of lithium-sulfur batteries (LSBs) remains restricted because of a severe polysulfide-shuttle effect and the insulating nature of sulfur. In this work, a kind of unique γ-Al2O3@C yolk-shell microspheres comprising carbon coating on the γ-Al2O3 yolk-shell microspheres were synthesized using organic adsorpting and in-situ thermal reduction methods, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM). It was demonstrated that the γ-Al2O3@C yolk-shell microspheres could encapsulate the polysulfides and increase the sulfur utilization. Accordingly, γ-Al2O3@C yolk-shell microspheres cathode achieved high initial discharge capacity of 1046.9â¯mAh gâ1, excellent discharge capacity (765.5â¯mAh gâ1) after 70 cycles (the capacity retention was about 73%) and superior rate performance. In addition, the appropriate C content was proved to be an important factor in the influence of electrochemical performances. Hence, our present method paves a new path to improve the performance of LiS batteries.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 221, 1 January 2019, Pages 258-262
Journal: Materials Chemistry and Physics - Volume 221, 1 January 2019, Pages 258-262
نویسندگان
Yao Wu, Qi Xiao, Suping Huang, Kun Wang,