Nickel antigorite synthesis and carbon tubular nanostructures formation on antigorite-based nickel particles by acetylene decomposition

Acetylene decomposition performed around 600 °C on these samples yield small amounts of carbon tubular nanostructures (nanotubes and nanofilaments). However, we have found that, whatever the temperature, carbon tubular nanostructures growth (tip growth mechanism) is favoured on the destructured regions of the material where the Ni particles are weakly bound to the support. Higher density of tubular nanostructures is consequently observed for the higher temperature samples. We attributed this behaviour to the fact that the strongly bound anchored Ni particles mainly exhibit (1 1 1)-type faces, which are known to promote carbon precipitation. This would lead to coking when particles are not able to rearrange (as it is the case for the anchored particles) whereas carbon tubular nanostructures may grow on weakly bound particles that are able to rearrange.