کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10239004 | 46017 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mesoporous materials from zeolite seeds as supports for nickel tungsten sulfide active phases
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Mesoporous materials from zeolite seeds as supports for nickel tungsten sulfide active phases Mesoporous materials from zeolite seeds as supports for nickel tungsten sulfide active phases](/preview/png/10239004.png)
چکیده انگلیسی
MCM-41 aluminosilicate mesostructures (Si/Al = 18) with hexagonal long-range order were assembled from protozeolitic nanoclusters (zeolite seeds) that normally nucleate the crystallization of β-zeolite (BEA). Depending on the duration of the thermal treatment leading to the zeolite seeds, different acidic materials can be obtained. For short pre-treatment duration, the material presents the main characteristics of the MCM-41, whereas for longer pre-treatment duration, there is a gradual transition to a mostly zeolitic one. Hydrocracking of n-decane was carried out on catalysts composed of a sulfided nickel tungsten phase supported on various β-MCM-41 supports as well as on an amorphous silica-alumina and an AlSBA-15 material. The hydrocracking properties of the catalysts are related to the nature of the β-ÐCÐ-41 and vary from the comportment of silica-alumina materials to the one of a zeolite. The nickel-tungsten catalyst supported on β-MCM-6 (6 h pre-treatment for the zeolite seeds solution) is more active and more selective toward isomerization than the catalyst supported on a commercial silica-alumina support.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 294, Issue 1, 4 October 2005, Pages 59-67
Journal: Applied Catalysis A: General - Volume 294, Issue 1, 4 October 2005, Pages 59-67
نویسندگان
Shuangqin Zeng, Juliette Blanchard, Michèle Breysse, Yahua Shi, Xintian Su, Hong Nie, Dadong Li,