کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10244475 | 47690 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
In situ investigations of structure-activity relationships of a Cu/ZrO2 catalyst for the steam reforming of methanol
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: In situ investigations of structure-activity relationships of a Cu/ZrO2 catalyst for the steam reforming of methanol In situ investigations of structure-activity relationships of a Cu/ZrO2 catalyst for the steam reforming of methanol](/preview/png/10244475.png)
چکیده انگلیسی
Structure-activity relationships of a nanostructured Cu/ZrO2 catalyst for the steam reforming of methanol (MSR) were investigated under reaction conditions by in situ X-ray absorption spectroscopy (XAS) and X-ray diffraction (XRD) combined with on-line mass spectrometry (MS). Temperature-programmed activation by reduction in hydrogen or by reduction in a mixture of methanol and water (feed) was studied by time-resolved Cu K edge XANES and TG/DSC/MS measurements. Small and disordered CuO particles were identified as the main copper phase present in the precursors. After extended time on stream and treatment at 673 K in hydrogen, no significant sintering of the copper particles or deactivation of the reduced Cu/ZrO2 catalysts was detected, indicating a superior stability of the material. The initially low steam-reforming activity of the Cu/ZrO2 catalyst after reduction in hydrogen could be significantly increased by a temporary addition of oxygen to the feed. This increased activity after oxidative treatment is correlated with an increasing amount of oxygen in the copper particles. 63Cu NMR studies detected only a minor degree of microstrain in the active copper phase of the Cu/ZrO2 catalyst. The decreased reducibility of CuO/ZrO2, the low degree of microstrain, and the correlation between the amount of oxygen remaining in the copper particles and the catalytic activity indicate a different metal support interaction compared with Cu/ZnO catalysts.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 233, Issue 2, 25 July 2005, Pages 297-307
Journal: Journal of Catalysis - Volume 233, Issue 2, 25 July 2005, Pages 297-307
نویسندگان
A. Szizybalski, F. Girgsdies, A. Rabis, Y. Wang, M. Niederberger, T. Ressler,