کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10244550 | 47694 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
TiO2 nanotube-supported ruthenium(III) hydrated oxide: A highly active catalyst for selective oxidation of alcohols by oxygen
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
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چکیده انگلیسی
Ruthenium(III) hydrated oxide was deposited onto the surface of TiO2 nanotubes via ion exchange followed by alkali treatment. The catalytic activity of Ru(III)/TiO2 catalyst for the selective oxidation of alcohols by oxygen was studied in a continuous multichannel, compact reactor. It was found that the activity of Ru(III)/TiO2 (turnover frequency [TOF] ⩽ 450 hâ1) is greater than that of a recently reported Ru(III)/Al2O3 catalyst (TOF = 335 hâ1), and that the ruthenium loading could exceed 8 wt% without any significant loss of specific catalytic activity. High-resolution transmission electron microscopy and X-ray diffraction data show that ruthenium is highly dispersed on both the inner and the outer surfaces of the mesoporous TiO2 nanotubes with the diameter of nanoparticles between 1.2 and 2.4 nm, and is easily accessible by reactant molecules.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 235, Issue 1, 1 October 2005, Pages 10-17
Journal: Journal of Catalysis - Volume 235, Issue 1, 1 October 2005, Pages 10-17
نویسندگان
Dmitry V. Bavykin, Alexei A. Lapkin, Pawel K. Plucinski, Jens M. Friedrich, Frank C. Walsh,