کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10244692 | 47699 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A new, alternative, halogen-free synthesis for the fragrance compound Melonal using zeolites and mesoporous materials as oxidation catalysts
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
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چکیده انگلیسی
At present Melonal (2,6-dimethyl-5-hepten-1-al) fragrance is industrially produced by a Darzens reaction from 6-methyl-5-hepten-2-one, with ethylchloroacetate as reagent. We present here a novel halogen-free synthesis strategy that involves the chemoselective oxidation of Citral (3,7-dimethyl-6-octen-1-al), a common compound in the fragrance industry, with H2O2 and Sn-Beta or Sn-MCM-41 as catalysts. The performance of tin Lewis acid sites is compared with other potential catalytic sites, and it is found that aluminium Brønsted acid sites and zirconium or titanium Lewis acid sites are less efficient and selective than Sn. In the case of Ti, epoxidation by-products could be found. The re-usability of Sn-Beta zeolite is discussed, as is the heterogeneity of the reaction.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 234, Issue 1, 15 August 2005, Pages 96-100
Journal: Journal of Catalysis - Volume 234, Issue 1, 15 August 2005, Pages 96-100
نویسندگان
Avelino Corma, Sara Iborra, MarÃa Mifsud, Michael Renz,