کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10267047 | 459437 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Novel KOH electrolyte for one-step electrochemical synthesis of high purity solid K2FeO4: Comparison with NaOH
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
An electrosynthesis from an iron wire gauze in KOH electrolyte is first presented for the in situ direct synthesis of the solid K2FeO4, with a highest efficiency of 73.2%, purities of 95.3-98.1% and a highest yield of 49 g lâ1 K2FeO4 at 65 °C, which is far better than that in NaOH electrolyte as a whole. A variety of electrolysis conditions including cell configuration, applied current density, temperature and electrolyte concentration have been explored. The in situ and ex situ electrochemically directly synthesized K2FeO4 powders exhibit similar IR absorption spectra and XRD patterns to the chemical synthesized K2FeO4 but different crystal morphologies.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 7, Issue 6, June 2005, Pages 607-611
Journal: Electrochemistry Communications - Volume 7, Issue 6, June 2005, Pages 607-611
نویسندگان
Weichun He, Jianming Wang, Haibo Shao, Jianqing Zhang, Chu-nan Cao,