کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10267331 459451 2005 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Integration of electrochemical generator and detector of nitric oxide with the aid of the iron porphyrin
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Integration of electrochemical generator and detector of nitric oxide with the aid of the iron porphyrin
چکیده انگلیسی
An electrochemical cell of generating nitric oxide (NO) was constructed in order to realize the catalytic reaction of nitrite by iron porphyrin [Y. Chi, J. Chen, K. Aoki, Inorg. Chem. 43 (2004) 8437]. The cell was composed of the generator of the iron porphyrin-including Nafion®-coated electrode, the ion-exchange membrane, and the electrochemical detector of NO. The reduction of iron porphyrin in the presence of nitrite at the generator coordinates nitrite to form the NO-included complex, of which oxidation releases NO. The water-dissolved NO diffused to the detector through the membrane to block nitrite. It was detected by voltammetry with the aid of the oxidative catalytic reaction of iron porphyrin.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 7, Issue 12, December 2005, Pages 1205-1208
نویسندگان
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