Interfacial reaction and mechanical reliability of PTH solder joints with different solder/surface finish combinations

The effects of minor Ni addition (0.05 wt.%) on the microstructures and mechanical reliability of the lead-free solder joints used in the pin through hole (PTH) components were carefully investigated using a scanning electron microscope (SEM), a field-emission electron probe x-ray microanalyzer, and a pull tester. The PTH walls (i.e., Cu) of printed circuit boards (PCBs) were coated with organic solderability preservative (OSP) or electroless nickel/immersion gold (ENIG) surface finish before soldering. During soldering, the pins of the electronic components were first inserted into the PTHs deposited with OSP or ENIG, and then joined using a Sn-3Ag-0.5Cu (SAC) solder bath through a typical wave-soldering process. After wave soldering, a rework (the second wave soldering) was performed, where an SAC or Sn-0.7Cu-0.05Ni (SCN) solder bath was employed. The SCN joints were found to possess a higher tensile strength than the SAC ones in the OSP case. The sluggish growth of Cu3Sn, along with few Kirkendall voids at the solder/Cu interface caused by minor Ni addition into the solder alloy (i.e., SCN), was believed to be the root cause responsible for the increase in the strength value. However, the mechanical strength of the PTH components was revealed to be insensitive to the solder composition in the alternative case where an ENIG was deposited over the PTH walls. The implication of this study revealed that minor addition of Ni into the solder is beneficial for the solder/Cu joints, but for the solder/Ni(P) joints.