کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10377624 | 880740 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dithiophosphinate-pyrite interaction: Voltammetry and DRIFT spectroscopy investigations at oxidizing potentials
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Dithiophosphinate-pyrite interaction: Voltammetry and DRIFT spectroscopy investigations at oxidizing potentials Dithiophosphinate-pyrite interaction: Voltammetry and DRIFT spectroscopy investigations at oxidizing potentials](/preview/png/10377624.png)
چکیده انگلیسی
The electrochemistry of dithiophosphinate (DTPI) adsorption on pyrite was investigated by cyclic voltammetry (CV) and diffuse reflectance infrared Fourier transformation (DRIFT) spectroscopy at oxidizing potentials under acid, neutral, and alkaline conditions. CV study showed that the mineral surface was covered by porous ferric oxyhydroxide species. Irreversible DTPI adsorption on the pyrite surface and inhibition of electron transfer to some extent were also observed from electrochemical work. Major collector species were determined from DRIFT spectroscopy study as adsorbed collector compound, DTPI°, and dimer of dithiophosphinate, (DTPI)2. Maximum adsorption density of DTPI was obtained in acid solution. It decreased sharply under neutral and alkaline conditions due to heavy surface oxidation at higher pH.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 288, Issue 2, 15 August 2005, Pages 319-324
Journal: Journal of Colloid and Interface Science - Volume 288, Issue 2, 15 August 2005, Pages 319-324
نویسندگان
Taki Güler,