کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10378080 | 880749 | 2005 | 14 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
TPR, TPO, and TPD examinations of Cu0.15Ce0.85O2ây mixed oxides prepared by co-precipitation, by the sol-gel peroxide route, and by citric acid-assisted synthesis
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: TPR, TPO, and TPD examinations of Cu0.15Ce0.85O2ây mixed oxides prepared by co-precipitation, by the sol-gel peroxide route, and by citric acid-assisted synthesis TPR, TPO, and TPD examinations of Cu0.15Ce0.85O2ây mixed oxides prepared by co-precipitation, by the sol-gel peroxide route, and by citric acid-assisted synthesis](/preview/png/10378080.png)
چکیده انگلیسی
Temperature-programmed reduction (TPR), oxidation (TPO), and desorption (TPD) studies were performed on three copper-ceria mixed oxide samples having the same nominal composition, Cu0.15Ce0.85O2ây, but prepared in three different ways: by co-precipitation, the sol-gel peroxide route, and the sol-gel citric acid route. The obtained results reveal that despite a drastic initial drop in specific surface area after consecutive redox cycles, the hydrogen consumption remains constant. This is because CuO is highly dispersed over the surface of CeO2 nanocrystallites and remains highly dispersed even after the agglomeration of CeO2 nanocrystallites in a denser secondary structure. The dispersed CuO is reduced to Cu0 during the TPR, forming agglomerated metal particles on the surface of partially reduced CeO2. However, after subsequent temperature-programmed oxidation all the Cu0 is oxidized back into CuO and redispersed over the CeO2 crystallites.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 285, Issue 1, 1 May 2005, Pages 218-231
Journal: Journal of Colloid and Interface Science - Volume 285, Issue 1, 1 May 2005, Pages 218-231
نویسندگان
Albin Pintar, Jurka Batista, Stanko HoÄevar,