کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10378397 880754 2005 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influence of configuration of carboxylic acid capping ligands on the salt-induced aggregation of gold clusters
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
Influence of configuration of carboxylic acid capping ligands on the salt-induced aggregation of gold clusters
چکیده انگلیسی
Oxalic acid (Ox) and 1,2,3,4-cyclobutanetetracarboxylic acid (CBTCA) were employed as capping ligands in the preparation of gold colloids. FTIR indicated that Ox adopted a linear configuration through one oxygen atom and one gold atom, while CBTCA adopted a bridge configuration through two oxygen atoms and two gold atoms. Ox-gold colloids exhibited aggregation upon addition of NaClO4, while they remained as isolated particles upon NaCl. For CBTCA-gold colloids, not NaClO4 but NaCl resulted in aggregation. The reversed results were considered to have been influenced by the different configurations of Ox and CBTCA, which were combined results of the Lewis basicity and steric hindrance of the added ions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 283, Issue 2, 15 March 2005, Pages 440-445
نویسندگان
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