کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10390045 | 884447 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of extraction resin containing 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester and its performance for separation of rare earths (Gd, Tb)
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
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چکیده انگلیسی
An extraction resin, with styrene-divinyl benzene copolymer as the supporter and 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (HEH[EHP]) as the extractant, was synthesized by suspension polymerization, and its performance in separating rare earths, such as gadolinium and terbium, was investigated. Especially, the effect of the stirring speed and the ratio of porogenic-agents in synthesizing the resin were examined. It was concluded that the optimal condition for synthesizing the resin is a stirring speed of 3000 rpm with a 10/10 wt.% ratio of toluene/n-heptane as the porogenic-agents. It was determined that the porogenic-agent could only increase the surface area of extraction resin and did not influence the particle size. Synthesis under these conditions will yield 0.628 g HEH[EHP]/g resin, with a resolution value,αGdTb of 0.727 and longest effluent ranges of 675 ml. The extracted Gd and Tb were both 99.9% pure.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 43, Issue 2, May 2005, Pages 111-116
Journal: Separation and Purification Technology - Volume 43, Issue 2, May 2005, Pages 111-116
نویسندگان
Jin-Seo Park, Choon Han, Jin-Young Lee, Sung-Don Kim, Joon-Soo Kim, Jung-Ho Wee,