کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10425087 | 906719 | 2012 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of polybenzoxazine-functionalized Fe3O4 nanoparticles through in situ Diels-Alder polymerization for high performance magnetic polybenzoxazine/Fe3O4 nanocomposites
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
سایر رشته های مهندسی
مهندسی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Preparation of polybenzoxazine-functionalized Fe3O4 nanoparticles through in situ Diels-Alder polymerization for high performance magnetic polybenzoxazine/Fe3O4 nanocomposites Preparation of polybenzoxazine-functionalized Fe3O4 nanoparticles through in situ Diels-Alder polymerization for high performance magnetic polybenzoxazine/Fe3O4 nanocomposites](/preview/png/10425087.png)
چکیده انگلیسی
Hybrids and nanocomposites of polymer and magnetic Fe3O4 nanoparticles have been utilized as magnetically-responsive materials and magnetically-directed nanoparticles. In this work, we prepare polymer-functionalized Fe3O4 nanoparticles through in situ Diels-Alder polymerization using maleimide-functionalized Fe3O4 nanoparticle as a precursor. Polybenzoxazine-functionalized Fe3O4 nanoparticles (MNP-PBz) have been obtained and characterized with Fourier Transform Infrared, X ray photoelectron, and Raman spectroscopies. The high saturation magnetization value of 51.9 emu gâ1 of the MNP-PBz nanoparticles demonstrates its superparamagnetism. Moreover, MNP-FBz has been utilized as a nanofiller for preparation of cured PBz/MNP-PBz nanocomposites, which contain various MNP-PBz contents of 67, 50, 33, and 17 wt.%. The sample of PBz/MNP-PBz-67 shows a storage modulus of 8.0 GPa, a saturation magnetization value of 37.6 emu gâ1, and a glass transition temperature above 380 °C. As a result, the PBz/MNP-PBz nanocomposites could be classified as magnetically-responsive high performance materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Science and Technology - Volume 72, Issue 13, 22 August 2012, Pages 1562-1567
Journal: Composites Science and Technology - Volume 72, Issue 13, 22 August 2012, Pages 1562-1567
نویسندگان
Chuan-Shao Wu, Ting-Hsuan Kao, Hsieh-Yu Li, Ying-Ling Liu,