کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10536295 962067 2005 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemical behavior of l-cysteine and its detection at carbon nanotube electrode modified with platinum
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Electrochemical behavior of l-cysteine and its detection at carbon nanotube electrode modified with platinum
چکیده انگلیسی
The electrochemical behavior of l-cysteine (CySH) on platinum (Pt)/carbon nanotube (CNT) electrode was investigated by cyclic voltammetry. CNTs used in this study were grown directly on graphite disk by chemical vapor deposition. Pt was electrochemically deposited on the activated CNT/graphite electrode by electroreduction of Pt(IV) complex ion on the surface of CNTs. Among graphite, CNT/graphite, and Pt/CNT electrodes, improved electrochemical behavior of CySH oxidation was found with Pt/CNT electrode. On the other hand, a sensitive CySH sensor was developed based on Pt/CNT/graphite electrode. A linear calibration curve can be observed in the range of 0.5 μM-0.1 mM. The detection limit of the Pt/CNT electrode is 0.3 μM (signal/nose = 3). Effects of pH, scan rate, and interference of other oxidizable amino acids were also investigated and discussed. Additionally, the reproducibility, stability, and applicability of the Pt/CNT electrode were evaluated.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Analytical Biochemistry - Volume 339, Issue 1, 1 April 2005, Pages 29-35
نویسندگان
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