UV-vis absorption spectroscopic study for on-line monitoring of uranium concentration in LiCl-KCl eutectic salt

UV-vis absorption spectroscopy of uranium in LiCl-KCl eutectic salt at 773 K was studied for the on-site use in pyrochemical process. Uranium(III) chloride was electrochemically prepared from uranium metal in LiCl-KCl eutectic salt at 773 K by using chronopotentiometry. Three absorption peak positions were selected and calibrated for the quantitative analysis of uranium in the molten salt medium. The molar absorptivity and minimum detectable concentration for the selected wavelength were obtained with a confidence level of 99%.