کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10556878 | 968435 | 2011 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Simple and sensitive fluorescence sensor for detection of potassium ion in the presence of high concentration of sodium ion using berberine-G-quadruplex complex as sensing element
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
In this work, a novel potassium ion (K+) sensor is presented using berberine-G-quadruplex complex as a fluorescent probe. This sensor is based on the K+that can induce the G-rich DNA to form G-quadruplex conformation. The G-quadruplex can bind berberine to form berberine-G-quadruplex complex, resulting in remarkable enhancement of fluorescence emission of the berberine-G-quadruplex system. In the presence of 800Â mM sodium ion (Na+), the fluorescence of the berberine-G-quadruplex complex increased linearly with increasing K+ concentration in the range of 0.005-1.0Â mM. The turn-on fluorescent assay is simple, inexpensive, and highly sensitive. We observed that Na+ in 10,000-fold molar excess does not interfere. The molecular mechanisms which produce enhanced fluorescence of berberine were discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microchemical Journal - Volume 99, Issue 2, November 2011, Pages 503-507
Journal: Microchemical Journal - Volume 99, Issue 2, November 2011, Pages 503-507
نویسندگان
Yanyan Liu, Baoxin Li, Dongmei Cheng, Xiaoyan Duan,