کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10567351 | 972646 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Selective response of dopamine in the presence of ascorbic acid at multi-walled carbon nanotube modified gold electrode
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
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چکیده انگلیسی
The acid-treated multi-walled carbon nanotubes (MWNTs), which were modified on the surface of gold electrode, offers substantial improvements in voltammetric sensitivity and selectivity towards the determination of dopamine (DA). It can inhibit the voltammetric response of ascorbic acid (AA) while the redox reaction of dopamine is promoted. When a differential pulse voltammetric (DPV) technique was used, the peak separation between DAs and AAs was 244 mV. Based on this, a selective method could be constructed to detect DA in the presence of 1000 times higher concentration of AA. The effect of various experimental parameters on the voltammetric response of dopamine was investigated. Under the chosen conditions, the peak currents are correspondent linearly to the concentrations of DA in the range of 5Ã10â7â¼4Ã10â4 mol Lâ1 with a limit of detection of 2Ã10â7 mol Lâ1. The proposed method can be applied to detect DA in real samples.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Bioelectrochemistry - Volume 67, Issue 1, September 2005, Pages 109-114
Journal: Bioelectrochemistry - Volume 67, Issue 1, September 2005, Pages 109-114
نویسندگان
Ping Zhang, Fang-Hui Wu, Guang-Chao Zhao, Xian-Wen Wei,