Syntheses, characterization and crystal structures of diorganotin compounds with 2-mercaptopyrimidine and 4-amino-2-mercaptopyrimidine

Six diorganotin compounds with 4-amino-2-mercaptopyrimidine (HSapym) and 2-mercaptopyrimidine (HSpym) of the type, [R2SnClmLn] · Y (when n = m = 1: L = Spym, R = CH3, Y = 0, 1; R = Bu, Y = 0, 2; L = Sapym, R = Ph, Y = EtOH, 3; when n = 2, m = 0: L = Spym, R = PhCH2, Y = 0, 4; L = Sapym, R = Bu, Y = 2MeOH, 5; R = PhCH2, Y = 3MeOH, 6) have been synthesized. All the compounds 1-6 have been characterized by elemental, 1H NMR spectroscopy and X-ray crystallography diffraction analyses.