کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10578623 | 979761 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mononuclear and binuclear ruthenium(II) complexes with 4-(phenyl) thiosemicarbazone of benzaldehyde: A discussion on the relative stabilities of the four-membered and five-membered chelate rings formed by the ligand
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Three new ruthenium complexes of formulae cis-[Ru(PPh3)2(BzTscbz)2] (1a), [Ru2(PPh3)2(BzTscbz)4] (1b) and [Ru(PPh3)2(BzTscHbz)2](ClO4)2 (2) have been synthesized and characterized by various physicochemical methods including X-ray structure determination for 1a and 1b. The relative stabilities of the four-membered versus five-membered chelate ring formed by the ligand BzTscbz is discussed on the basis of the experimental results and some semi-empirical as well as DFT calculations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 24, Issue 14, 3 October 2005, Pages 1861-1868
Journal: Polyhedron - Volume 24, Issue 14, 3 October 2005, Pages 1861-1868
نویسندگان
Dipankar Mishra, Subhendu Naskar, Michael G.B. Drew, Shyamal Kumar Chattopadhyay,