کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10578641 979766 2005 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and structures of two new copper(II) coordination polymers with pyridyl ligands
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and structures of two new copper(II) coordination polymers with pyridyl ligands
چکیده انگلیسی
The reaction of Cu(OAc)2 · H2O with bpa (bpa = 1,2-bis(4-pyridyl)ethane) in CH3OH afforded the complex [Cu2(OAc)4(bpa) · 2H2O]n (1) while the reaction of CuSO4 · 5H2O with bpen (bpen = trans-bis(4-pyridyl)ethene) in CH3OH afforded the complex [Cu(bpen)(H2O)3(SO4) · 4H2O]n (2). Complexes 1 and 2 form molecular chains which, linking by C-H⋯π, π-π interactions and hydrogen bondings, line up in layers with each layer crossing the layer beneath to form rhombic channels. Thermal gravimetric analyses and differential scanning calorimetry were carried out to investigate their thermal properties.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 24, Issue 12, 25 August 2005, Pages 1497-1502
نویسندگان
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