کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10578707 979771 2005 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and crystal structures of sterically hindered lithium-1-azaallyls and a diazahexatriene
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and crystal structures of sterically hindered lithium-1-azaallyls and a diazahexatriene
چکیده انگلیسی
The lithium-1-azaallyl complexes [LiN(Ar)C(R)CHR′(D)] 1 and the diazahexatriene 2 were obtained in moderate yields from LiCHR2 or LiCH(R)Ph(tmen) and ArNC [Ar=C6H3(Pri2-2,6) or C6H3(But2-2,5)]. All compounds were characterized by NMR spectroscopy and single crystal X-ray crystallography. 1b-1d were found to be monomeric in the solid state with 1b adopting an unusual anti-conformation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 24, Issue 8, 2 June 2005, Pages 958-967
نویسندگان
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