کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10578771 979782 2005 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and properties of iron (II) quinoline-2-carboxylates, crystal structure of trans-diaquabis(quinoline-2-carboxylato)iron (II) bis(dichloromethane) solvate
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and properties of iron (II) quinoline-2-carboxylates, crystal structure of trans-diaquabis(quinoline-2-carboxylato)iron (II) bis(dichloromethane) solvate
چکیده انگلیسی
Reaction between metallic iron and quinoline-2-carboxylic acid (Hquin-2-c) in dichloromethane yielded the amorphous Fe(quin-2-c)2 (1). In the presence of a small amount of water, X-ray suitable crystals of [Fe(quin-2-c)2(H2O)2] · 2CH2Cl2 (2) were obtained. The structure of 2 is compared with the literature reported [Fe(quin-2-c)2(H2O)2] · 2EtOH 2H2O (3), a system of strong hydrogen bonds in 2 and 3 create the 2D framework. The spectral and magnetic properties of all compounds are reported.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 24, Issue 3, 17 February 2005, Pages 407-412
نویسندگان
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