کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10618721 | 988184 | 2005 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Excited state dynamics in alternating polyfluorene copolymers
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
بیومتریال
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Excited state dynamics in alternating polyfluorene copolymers Excited state dynamics in alternating polyfluorene copolymers](/preview/png/10618721.png)
چکیده انگلیسی
We present the excited state dynamics of the low band gap alternating polyfluorene copolymer, DiO-PFDTBT. The copolymer structure is an alternating sequence of donor and acceptor units consisting of 9,9-dioctyl-9H-fluorene and 4,7-di-thiophen-2-yl-benzo[1,2,5]thiadiazolyl units. Calculations have predicted that the first excited state has charge transfer character, while the second strongly allowed excited state is a delocalized Ï-conjugated state. We show that the excited state dynamics involves internal conversion (IC) from the second strongly allowed excited state to the first excited state. Furthermore, excitation energy transfer (EET) on the â¼1-10Â ps time scale is observed as well as a subsequent formation of a stabilized long-lived emissive state, which has a decay time of 3.25Â ns. The origin of this stabilized state is discussed in relation to the intrinsic charge transfer nature of the DiO-PFDTBT.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Synthetic Metals - Volume 155, Issue 2, 15 November 2005, Pages 262-265
Journal: Synthetic Metals - Volume 155, Issue 2, 15 November 2005, Pages 262-265
نویسندگان
Kim G. Jespersen, Arkady Yartsev, Thorbjörn Pascher, Villy Sundström,