کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10618744 | 988184 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electronic and structural instabilities of mixed-stack organic charge-transfer salts
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
بیومتریال
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Electronic (valence) and structural (Peierls) instabilities occur either separately or together in organic charge-transfer (CT) crystals with mixed stacks of donors (D) and acceptors (A). A Peierls-Hubbard model, HCT, with site D, A energies and linear electron-phonon coupling in a harmonic lattice is shown to provide a unified microscopic description and to distinguish between thermal and quantum Peierls transitions. Vibrational, magnetic and structural data are interpreted as thermal Peierls transitions in two ionic CT salts and as dimerized ground states with spin solitons in other salts. Quantum Peierls transitions are identified in largely neutral salts, and a neutral-ionic crossover is discussed in a salt with dipolar disorder that suppresses the Peierls instability. The coincident Peierls and neutral-ionic transition of tetrathiafulvalene-chloranil (TTF-CA) is another special case of HCT.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Synthetic Metals - Volume 155, Issue 2, 15 November 2005, Pages 357-364
Journal: Synthetic Metals - Volume 155, Issue 2, 15 November 2005, Pages 357-364
نویسندگان
Zoltán G. Soos, Sharon A. Bewick, Anna Painelli, Alberto Girlando,