The growth of nanophases in the clean room inside single-wall carbon nanotubes

The interior of single-wall carbon nanotubes is studied by filling fullerenes into the one-dimensional nanospace inside the tubes using different filling methods. Filling from solution is demonstrated as efficient as filling from the vapor phase. Evidence for successful filling comes from a transformation of the encapsulated carbon atoms to a secondary tube centered inside the primary tube. Isotope-labeled fullerenes are used to disentangle the Raman response from the two shells in double-wall carbon nanotubes.