کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10629410 | 991063 | 2016 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Colossal permittivity and low losses in Ba1-xSrxTiO3-δ reduced nanoceramics
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The oxalate route offers a controlled approach to synthesize pure Ba1-xSrxTiO3 (BST) (0 â¤Â x â¤Â 1) nanoparticles (Ï â 150 nm in diameter). Reduced BST dense nanoceramics were obtained by spark plasma sintering (SPS) and then annealed for a short time to reach colossal permittivity (ϵâ²r = 105) with low dielectric losses (tan δ = 0.03) at 1 kHz and 300 K. The effects of Ba-Sr substitution on structural, microstructural and electrical properties were analyzed. Comprehensive analysis of the electrical properties indicates that polaron hopping, mediated by Ti3+ ions and oxygen vacancies is the main contributing mechanism to colossal permittivity in Ba-rich BST compounds. Substitution of Ba by Sr reduced the contribution of polaron hopping and led to a decrease of real and imaginary parts of permittivity, while preserving interfacial polarization and yielding better temperature stability. The lowest temperature coefficient of capacitance, or TCC (variation of capacitance between 310 K and 450 K) value, i.e., 44 ppm Kâ1, is obtained for SrTiO3.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the European Ceramic Society - Volume 36, Issue 3, February 2016, Pages 567-575
Journal: Journal of the European Ceramic Society - Volume 36, Issue 3, February 2016, Pages 567-575
نویسندگان
Sébastien Dupuis, Soumitra Sulekar, Ji Hyun Kim, Hyuksu Han, Pascal Dufour, Christophe Tenailleau, Juan Claudio Nino, Sophie Guillemet-Fritsch,