کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10636824 | 993827 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Interpenetrating and non-interpenetrating 3-dimensional coordination polymer frameworks from multiple building blocks
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Interpenetrating and non-interpenetrating 3-dimensional coordination polymer frameworks from multiple building blocks Interpenetrating and non-interpenetrating 3-dimensional coordination polymer frameworks from multiple building blocks](/preview/png/10636824.png)
چکیده انگلیسی
Reaction of Co(NO3)2â
6H2O with the multidentate ligands benzene-1,3,5-tricarboxylate (btc) and the flexible bipyridyl ligand 1,2-bis(4-pyridyl)ethane (bpe) affords the 3-dimensional coordination polymers [Co3(btc)2(bpe)3(eg)2]â
(guests) 1, where eg = ethylene glycol, and [Co2(Hbtc)2(bpe)2]â
(bpe) 2. Both phases are comprised of infinite metal-carboxylate dimer chains, linked into 2-dimensional sheets by the bpe ligands. These sheets are further linked to adjacent sheets through covalent interactions, 1, or through hydrogen-bonding interactions, 2, to yield the 3-dimensional structures. Phase 1 exhibits solvent filled 1-dimensional pores, whereas 2 is triply-interpenetrated to form a dense solid array.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Sciences - Volume 7, Issue 12, December 2005, Pages 1522-1532
Journal: Solid State Sciences - Volume 7, Issue 12, December 2005, Pages 1522-1532
نویسندگان
Darren Bradshaw, Matthew J. Rosseinsky,