کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10638111 995352 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A effective flame retardant for epoxy resins based on poly(DOPO substituted dihydroxyl phenyl pentaerythritol diphosphonate)
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
A effective flame retardant for epoxy resins based on poly(DOPO substituted dihydroxyl phenyl pentaerythritol diphosphonate)
چکیده انگلیسی
Poly(DOPO substituted dihydroxyl phenyl pentaerythritol diphosphonate) (PFR) was synthesized via the reaction between 10-(2,5-dihydroxyl-phenyl)-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO-BQ) and pentaerythritol diphosphonate dichloride (SPDPC). The structures of PFR were characterized by Fourier transformed infrared (FTIR) spectroscopy and 1H nuclear magnetic resonance (1H NMR). Thermal degradation behaviors and flame retardant properties of the epoxy resin (ER)/PFR systems were investigated from the thermogravimetric analysis (TGA), UL-94 test and the limiting oxygen index (LOI) test. Moreover, the surface morphology of the char residue was studied by scanning electron microscopy (SEM). When the PFR content reached 10 wt%, the epoxy resin system met the UL-94 V0 classification and the LOI value of 30.2. The microscale combustion calorimetry (MCC) was used to evaluate the combustion behaviors of the ER/PFR. It was found that the addition of PFR obviously decreased the value of peak heat release rate and total heat release of the hybrids. The TGA results showed that the epoxy resin with 10 wt% PFR exhibited high char yields. The high char yields and the high limiting oxygen index values were found to certify the excellent flame retardancy of this phosphorus-containing epoxy resin.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 125, Issue 3, 15 February 2011, Pages 536-541
نویسندگان
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