کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10638233 | 995413 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of Ag/polyaniline nanocomposite via an in situ photo-redox mechanism
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
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چکیده انگلیسی
Silver/polyaniline nanocomposites are prepared via in situ reduction of silver salt in aniline by mild photolysis performed with 8Â W long wavelength (365Â nm) and short wavelength (254Â nm) radiation from UV lamp. Reduction of the silver salt in aqueous aniline leads to the formation of silver nanoparticles which in turn catalyze oxidation of aniline to polyaniline. Systematic observation of the progress of the reaction by means of absorption spectroscopy revealed that the reaction completes faster under the UV light of 254Â nm wavelength than the visible source of 365Â nm. The absorption bands of the reaction solution revealed that the bands at about 400-420Â nm due to benzonoid ring of the polyaniline are overlapped and red-shifted due to the presence of nano-silver in powdered state. A slightly broadened X-ray diffraction (XRD) pattern indicating, small particle size (â¼30Â nm), is consistent with cubic silver. Scanning electron microscopy (SEM) of the nanocomposite showed a uniform size distribution with spherical and granular morphology. Thermogravimetric analysis (TGA) showed that the composites have a higher degradation temperature than polyaniline alone.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 92, Issue 1, 15 July 2005, Pages 214-219
Journal: Materials Chemistry and Physics - Volume 92, Issue 1, 15 July 2005, Pages 214-219
نویسندگان
P.K. Khanna, Narendra Singh, Shobhit Charan, A. Kasi Viswanath,