کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10674947 | 1010578 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enhancement of copolymerization of itaconic acid with N-vinyl 2-pyrrolidone by radiation in the presence of cross-linking agent
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سطوح، پوششها و فیلمها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Enhancement of copolymerization of itaconic acid (IA) with N-vinyl 2-pyrrolidone (VP) by radiation in the presence of cross-linking agent was investigated. Hydrogels with varying IA content were prepared from the ternary systems N-vinyl 2-pyrrolidone/itaconic acid/water by irradiating with gamma-rays in the presence of a chemical cross-linker, ethylene glycol dimethacrylate (EGDMA) at ambient temperature. The incorporation of EGDMA into the ternary mixtures caused an increase in the amount of IA in the gel system up to a mole fraction of 13.7%. Hydrogels showed a typical pH response such as high pH swelling and low pH deswelling. Equilibrium volume swelling ratio at pH 7 was varied from 15-40 with changing the IA content in the gel system and irradiation dose. The equation recently modified by the authors for the determination of M¯c is observed to describe the swelling behaviour of P(VP/IA/EGDMA) networks containing relatively higher amount of charged units very well. In addition to the evaluation of M¯c from swelling data, the measurement of polymer solvent interaction parameter and the determination of the reaction yield of cross-links of the systems were examined.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms - Volume 234, Issue 3, June 2005, Pages 226-234
Journal: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms - Volume 234, Issue 3, June 2005, Pages 226-234
نویسندگان
M. Åen, A. Yakar,