کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
11005990 | 1498894 | 2018 | 18 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and characterization of a Cd compound for selectively sensing of nitro-explosives
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel luminescent metal-organic framework, [Cd2L(DMF)2(H2O)2]n (1), based on a chiral binaphthol derivative 2,2â²-diethoxy-1,1â²binaphthyl-4,4â²,6,6â²-tetracarboxylic acid (H4L) has been synthesized. This compound is a 4-connected node 3D network topology with the point symbol {6^6} and SQC topology type. Photoluminescence (PL) studies indicated that the fluorescence emission peak of complex 1 shows a blue-shift first and then a red-shift with the increase of solvent polarity. Significantly, complex 1 has a good response to the nitro-compounds and its quenching efficiency increases significantly with increasing number of gen-containing groups on explosives.308
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 96, October 2018, Pages 189-193
Journal: Inorganic Chemistry Communications - Volume 96, October 2018, Pages 189-193
نویسندگان
Yufei Wang, Kuan Gao, Jingjing Li, Liping Wang, Jie Wu,