کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
11262941 | 1802868 | 2019 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The spatial inhomogeneity and X-ray absorption spectroscopy of superconducting nanocrystalline boron doped diamond films
ترجمه فارسی عنوان
ناهمگنی فضایی و طیف سنجی جذب اشعه ایکس فیلم های الماس دو طرفه نانو کریستالین بور
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
چکیده انگلیسی
The local electrical conductivity and impurity band evolution in superconducting nanocrystalline boron doped diamond (BNCD) film are investigated using conducting atomic force microscopy (C-AFM) and X-ray absorption spectroscopy (XAS). C-AFM has been employed to investigate the local conductivity of superconducting BNCD with Tcâ¯=â¯4.3â¯K and upper critical field Hc2(0)â¯=â¯5.2â¯T. A high local electrical heterogeneity of the BNCD film as evidenced from the C-AFM profile points to the uneven boron uptake during the process of doping. C-AFM also revealed that grain boundaries are the highly conducting regions, possibly, due to the presence of p-type trans-polyacetylene along with the CC and CH bonds in the grain boundaries. From the in-depth XPS profiling of the B 1s spectra we confirmed the macroscopic uniformity of the boron concentration across the depth of BNCD layers. X-ray absorption spectroscopy (XAS) measurements near B K-edge and C K-edge showed formation of in-gap states as a result of heavy boron doping. Near C K-edge, bandgap states at 282.8â¯eV and 284.1â¯eV are found which are responsible for superconductivity in the BNCD film. This work explores the non-uniform boron doping and its effect on the conduction band structure of a superconducting BNCD film.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 466, 1 February 2019, Pages 498-502
Journal: Applied Surface Science - Volume 466, 1 February 2019, Pages 498-502
نویسندگان
Dinesh Kumar, G. Mangamma, Martando Rath, M.S. Ramachandra Rao,