کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1161682 1490449 2010 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
On the alleged non-existence of orbitals
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک و نجوم (عمومی)
پیش نمایش صفحه اول مقاله
On the alleged non-existence of orbitals
چکیده انگلیسی

I argue that the claim made by Scerri that in many-electron atoms, orbitals do not exist according to quantum mechanics, is incorrect, for it relies on the view that orbitals are entities. Orbitals are states, not entities, and their use in describing many-electron atoms should be seen as an approximation. The writings by Scerri and others on the issue of realism that are based on the claim therefore lead astray. I furthermore disentangle two issues that Scerri discusses in arguing for his claim: that of electron correlation and that of the Pauli principle. Finally, I point out that more generally there is a misconception in chemistry of what quantum states are.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Studies in History and Philosophy of Science Part B: Studies in History and Philosophy of Modern Physics - Volume 41, Issue 2, May 2010, Pages 178–182
نویسندگان
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