کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1193834 1492323 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Photodissociation and DFT investigation of V+(C2H4)n (n = 1–3) complexes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Photodissociation and DFT investigation of V+(C2H4)n (n = 1–3) complexes
چکیده انگلیسی

V+(C2H4)n were produced in a supersonic molecular beam by laser vaporization and were mass-analyzed with a reflectron time-of-flight mass spectrometer. V+(C2H4)n (n = 1–3) are predominant mass peaks in the mass spectrum. These species were mass-selected and photodissociated with 1064, 532 and 355 nm photons. Dissociation occurs by elimination of neutral ethene molecules. The fragment ion yields were studied as a function of photon fluxes in order to give insight into the dissociation mechanisms. The geometric structures, bond dissociation energies and ground electronic state of V+(C2H4)n (n = 1–4) were investigated using density functional theory (DFT). It has been confirmed that the most stable structures of V+(C2H4)n are all in quintet states.

V+(C2H4)n (n = 1–3) were photodissociated with 1064, 532 and 355 nm photons. The dissociation occurred by elimination of neutral ethene molecules.Figure optionsDownload high-quality image (61 K)Download as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Mass Spectrometry - Volume 295, Issues 1–2, 15 July 2010, Pages 36–42
نویسندگان
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