کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1194124 | 1492369 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A novel chemical reactor suited for studies of biophysical chemistry: Construction and evaluation of a selected ion flow tube utilizing an electrospray ion source and a triple quadrupole detection system
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel electrospray ion source/selected ion flow tube/triple quadrupole detector mass spectrometer has been constructed for the study of the kinetics and product distributions of reactions of a diverse array of electrosprayed ions reacting with neutral molecules. The electrospray source provides a near-universal source for ions of biological and other interests. The operation of the instrument is demonstrated with a selection of reactivity and kinetic measurements and threshold collision-induced dissociation determinations. Reactions investigated include H/D exchange between protonated bradykinin and deuterated ammonia, the protonation of the oligo-nucleotide anion [AGTCTG â 5H+]5â with HBr, the ozonolysis of Ca2+, the reaction of protonated phthalic anhydride with dimethyl disulfide, and the Argon collision-induced dissociation of Ba(C6H6)2+.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Mass Spectrometry - Volume 265, Issues 2â3, 1 September 2007, Pages 295-301
Journal: International Journal of Mass Spectrometry - Volume 265, Issues 2â3, 1 September 2007, Pages 295-301
نویسندگان
Gregory K. Koyanagi, Vladimir I. Baranov, Scott D. Tanner, Janna Anichina, Michael J.Y. Jarvis, Stefan Feil, Diethard K. Bohme,