کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1253206 | 971080 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, DNA-binding, and Photocleavage of 2,3-Di-2-pyridylquinoxaline-silver(I) Complex
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new dinuclear complex, [Ag(L)(CH3CN)]2(ClO4)2 2H2O(L=2,3-di-2-pyridylquinoxaline), was prepared and characterized by elemental analyses, IR spectroscopy, and single-crystal X-ray diffraction analyses. The interaction of the complex with calf thymus DNA(CT-DNA) was investigated by absorption, fluorescence spectroscopies, and viscosity measurement. The results suggested that the complex was bound to DNA via an intercalative mode. The intrinsic binding constant value Kb was found to be approximately 1.48Ã103 L·molâ1. Moreover, the Ag(I) complex could cleave the plasmid pUC19 DNA from the supercoiled Form I to the nicked Form II under irradiation at 365 nm.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Research in Chinese Universities - Volume 24, Issue 1, January 2008, Pages 15-19
Journal: Chemical Research in Chinese Universities - Volume 24, Issue 1, January 2008, Pages 15-19
نویسندگان
Xiu-li WANG, Jia-ni FANG, Yan-feng BI, Hong-yan LIN, Guo-cheng LIU,