کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1254039 | 971330 | 2015 | 6 صفحه PDF | دانلود رایگان |
In this paper, the precise construction on the structure of silicalite-1 microcapsules (S1) was specifically described. The interior carbon modifications and the outside mesoporous functionalizations were successfully conducted and each sample was characterized in detail. It was found that the carbon networks could be formed inside the zeolite microcapsules via the pretreatment of sugar injections. The uniformity of the distinct microcapsule could be regulated by adjusting the sugar concentrations. With the encapsulated Pt species inside the MSSs, the nano-particles could be dispersed well within the carbon network. On the other hand, during the fabrication of the mesoporous materials outside the microcapsules, the template and the acidity of the system could play an important role in determining the morphology of S1. Besides, the PDDA modification on the shell of S1 could help the combination of the meso-layer and the shell of S1 at nano-scale. The thickness of the outside mesopore could be modulated through the controlling of the silica content.
Zeolite microcapsules (S1) have been precisely modified with both mesoporouslayers at the external shell and amesoporous carbon networksinside the interior core.Figure optionsDownload as PowerPoint slide
Journal: Chinese Chemical Letters - Volume 26, Issue 11, November 2015, Pages 1409–1414