کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1254088 971340 2015 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A facile approach to tricyclo[6.4.0.04,9]-dodecane framework
ترجمه فارسی عنوان
یک رویکرد فشرده به چارچوب تریسیکلو [6.4.0.04.9] -دکانه
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
چکیده انگلیسی

The unusual tricyclo[6.4.0.04,9]dodecane framework was constructed in eight linear steps in 13% overall yield. An innovative strategy accessing the framework from bicyclo[3.3.1]nonanes was employed. The key steps involve a Robinson annulation, a base induced decarboxylation and epimerization in a single step, and an intramolecular alkylation.

The unusual tricyclo[6.4.0.04,9]dodecane framework was constructed in eight linear steps in 13% overall yield. An innovative strategy accessing the framework from bicyclo[3.3.1]nonanes was employed. The key steps involve a Robinson annulation, a base induced decarboxylation and epimerization in a single step, and an intramolecular alkylation. This approach not only provides an access to the tricyclo[6.4.0.04,9]dodecane framework, but also is a potential access to other types of cis-decalin bearing a 1,5-bridging skeleton.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 26, Issue 2, February 2015, Pages 238–242
نویسندگان
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