کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1254196 971354 2014 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Polystyrene–graphene oxide modified glassy carbon electrode as a new class of polymeric nanosensors for electrochemical determination of histamine
ترجمه فارسی عنوان
پلی استایرن اکسید گرافین اصلاح شده الکترودهای کربن شیشه ای به عنوان یک کلاس جدید از نانوسنسورهای پلیمری برای تعیین الکتروشیمیایی هیستامین
کلمات کلیدی
پلی استایرن، اکسید گرافن، سنسور پلیمری آمین بیوگرافی، فناوری نانو
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
چکیده انگلیسی

A simple and rapid protocol for the synthesis of polystyrene–graphene oxide nanocomposite (PS/GONC) was achieved for first time using an in situ polymerization method. PS/GONC modified glassy carbon electrode (PS/GONC/GCE) has been employed as an efficient nanosensor for the electrooxidation of histamine. The PS/GONC/GCE is used as an electrochemical nanosensors for monitoring histamine using differential pulse voltammetry techniques (detection limit 0.03 μmol/L). In addition, the prepared nanosensor was successfully applied to determine histamine in fish samples, yielding satisfactory results. The spiked recoveries were in the range of 98.2%–103.1%.

A facile and rapid synthesis of polystyrene–graphene oxide nanocomposite via in situ polymerization of styrene and graphene oxide is reported, which provides a path to a novel class of polymeric materials and their use in electrochemical sensing of histamine (a biogenic amine). Cyclic voltammetric studies indicated that the oxidation process of histamine is irreversible and diffusion controlled. The prepared nanocomposite shows excellent electroactivity for histamine oxidation.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 25, Issue 4, April 2014, Pages 655–658
نویسندگان
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