کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1254603 971382 2014 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of l-glucose and l-galactose derivatives from d-sugars
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Synthesis of l-glucose and l-galactose derivatives from d-sugars
چکیده انگلیسی

An efficient route to prepare l-glucose and l-galactose is described. The l-sugars are achieved by using the strategy of switching the functional groups at C1 and C5 of d-glucose and d-mannose. The oxidation and reduction of the silyl enol ether at C1 and the lead(IV) tetraacetate mediated oxidative decarboxylation at C5 are the key steps. l-Glucose and l-galactose are prepared in a convenient and inexpensive way.

An efficient route to prepare l-glucose and l-galactose derivatives by using the strategy of switching the functional groups at C1 and C5 of d-glucose and d-mannose, respectively, was developed. l-Sugars could be prepared on a large scale by this strategy with high overall yields.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 25, Issue 9, September 2014, Pages 1220–1224
نویسندگان
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