کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1254747 | 971390 | 2011 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A promising green method in cyclization reaction. Oxidation of 3-methylcatechol in the presence of 1,10-phenanthroline
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: A promising green method in cyclization reaction. Oxidation of 3-methylcatechol in the presence of 1,10-phenanthroline A promising green method in cyclization reaction. Oxidation of 3-methylcatechol in the presence of 1,10-phenanthroline](/preview/png/1254747.png)
چکیده انگلیسی
Electrochemical oxidation of 3-methylcatechol as a model compound has been studied in the presence of 1,10-phenanthroline as a bi-dentate nucleophile in water/acetonitrile (70/30, v/v) solution using cyclic voltammetry and controlled-potential coulometry. The results revealed that anodically generated 3-methylcyclohexa-3,5-diene-1,2-dione participates in inter and intramolecular Michael addition reactions with 1,10-phenanthroline and via an ECEC pathway converts to the corresponding heterocyclic compound. The present work has led to the development of a facile and one-pot method with high atom economy under ambient conditions and in an undivided cell using a carbon electrode.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 22, Issue 9, September 2011, Pages 1067–1070
Journal: Chinese Chemical Letters - Volume 22, Issue 9, September 2011, Pages 1067–1070
نویسندگان
Davood Nematollahi, Bita Dadpou,