کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1254755 971390 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Study on supported combined liquid membrane containing HEH(EH)P and HNO3 for trivalent gadolinium transfer
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Study on supported combined liquid membrane containing HEH(EH)P and HNO3 for trivalent gadolinium transfer
چکیده انگلیسی

A novel kind of supported combined liquid membrane (SCLM) has been studied for the Gd(III) transfer. SCLM contained polyvinylidene fluoride membrane (PVDF) as the liquid membrane support and renewal solution including HNO3 solution as the stripping solution and 2-ethyl hexyl phosphonic acid-mono-2-ethyl hexyl ester (HEH(EH)P) as the carrier dissolved in kerosene. The mixed solution of carrier and kerosene was membrane solution. The optimum transport conditions of Gd(III) were that concentration of HNO3 solution was 4.00 mol/L, concentration of carrier was 0.16 mol/L, and volume ratio of membrane solution to stripping solution was 30:30 of the renewal phase, and pH value was 4.80 of the feed phase. Under the optimum condition studied, when initial concentration of Gd(III) was 1.00 × 10−4 mol/L, the transfer rate of Gd(III) was 96.8% during 130 min.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 22, Issue 9, September 2011, Pages 1095–1098
نویسندگان
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