کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1254868 | 971396 | 2014 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and electrochemical performance of LiNi0.6Co0.2Mn0.2O2 as a concentration-gradient cathode material for lithium batteries Synthesis and electrochemical performance of LiNi0.6Co0.2Mn0.2O2 as a concentration-gradient cathode material for lithium batteries](/preview/png/1254868.png)
A well-ordered and spherical LiNi0.6Co0.2Mn0.2O2 cathode material was successfully synthesized from Ni and Mn concentration-gradient precursors via co-precipitation. The crystal structure, morphology and electrochemical properties of LiNi0.6Co0.2Mn0.2O2 were characterized by X-ray diffraction, scanning electron microscopy, energy-dispersive spectroscopy, and charge–discharge tests. The material delivered an initial discharge capacity of 174.3 mAh/g at 180 mA/g (1 C rate) between 2.8 and 4.3 V and more than 93.1% of that was retained after 100 cycles. In addition, it also exhibited excellent rate capability, high cut-off voltage and temperature performance.
Spherical and well-ordered layer-structured LiNi0.6Co0.2Mn0.2O2 cathode material with Ni and Mn concentration-gradient had been successfully prepared by a hydroxide co-precipitated method. The material delivers an initial discharge capacity of 174.3 mAh/g at 180 mA/g (1 C rate) between 2.8 and 4.3 V, more than 93.1% of that was retained after 100 cycles. Besides, it also exhibited excellent rate capability, high cut-off and temperature performance.Figure optionsDownload as PowerPoint slide
Journal: Chinese Chemical Letters - Volume 25, Issue 6, June 2014, Pages 883–886