کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1255123 | 971407 | 2012 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Insights on the mechanism for synthesis of methylenedianiline from aniline and formaldehyde through HPLC–MS and isotope tracer studies
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Insights on the mechanism for synthesis of methylenedianiline from aniline and formaldehyde through HPLC–MS and isotope tracer studies Insights on the mechanism for synthesis of methylenedianiline from aniline and formaldehyde through HPLC–MS and isotope tracer studies](/preview/png/1255123.png)
چکیده انگلیسی
The mechanism for synthesis of 4,4-methylenedianiline (MDA) via condensation reaction of aniline with formaldehyde has been studied extensively in this paper. The intermediate and by-products were isolated and identified. The combination of isotope labeling and HPLC–MS characterizations disclosed that the reaction proceeded through an SN2 reaction mechanism. Moreover, the effect of aniline/formaldehyde molar ratio on the formation of MDA was investigated. This work would be of significance to understand the reaction mechanism deeply and provide valuable information for further improving the yield of desired product.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 23, Issue 11, November 2012, Pages 1254–1258
Journal: Chinese Chemical Letters - Volume 23, Issue 11, November 2012, Pages 1254–1258
نویسندگان
Chen Ye Wang, Hui Quan Li, Li Guo Wang, Yan Cao, Hai Tao Liu, Yi Zhang,